
* A purple-inclined red (crimson) and an orange-inclined red (scarlet)
* A green-inclined yellow (practically speaking, "spring green") and an orange-inclined yellow ("yellow")
* A purple-inclined blue (ultramarine) and a green-inclined blue (cerulean)
* White to make light tones (don't worry about black)
And these let me get almost all the spectral colors because, I think, the pigment grains don't interfere and don't cause subtractive mixing (there was some sketchy explanation about light bouncing between different pigment particles before bouncing properly back from the canvas). There are gaps due to the lack of any pure primary color, which we basically give up on being able to buy.
Many children were incorrectly taught that Red, Yellow and Blue were "primary" colours from which you could make any other colour: wrong. Fotunately we have better teaching now.
I like some of the comments here: https://nitaleland.blogspot.com/2005/10/urban-myth-blue-and-...
https://www.goodreads.com/book/show/2103727.Blue_and_Yellow_...
You can't subtractively mix all colors from three practical 'primaries'
If you mix Cadmium Yellow and Ultramarine Blue you get something yucky and greyish. With Hansa Yellow and Cerulean Blue on the other hand you can get a good green but that blue won't make a good violet when mixed with Cadmium Red Light.
The color mixing rules taught in elementary school don't really work and you need roughly 12 primaries to mix any arbitrary color.